Topic 3
Oxidizing and Reducing Agents: A Brief Overview
Oxidizing agents and reducing agents are substances involved
in redox reactions (reduction-oxidation reactions). These reactions involve the
transfer of electrons between chemical species.
Oxidizing Agents
● Definition: Oxidizing agents are substances that accept
electrons from other substances.
● Process: When an oxidizing agent accepts electrons, it
becomes reduced.
● Examples:
○ Oxygen (O₂)
○ Hydrogen peroxide
(H₂O₂)
○ Potassium permanganate
(KMnO₄)
○ Chlorine (Cl₂)
○ Nitric acid (HNO₃)
Reducing Agents
● Definition: Reducing agents are substances that donate
electrons to other substances.
● Process: When a reducing agent donates electrons, it
becomes oxidized.
● Examples:
○ Hydrogen (H₂)
○ Carbon monoxide (CO)
○ Sodium (Na)
○ Magnesium (Mg)
○ Sulfur dioxide (SO₂)
Key Points
● Redox Reactions: In redox reactions, both oxidation and
reduction occur simultaneously.
● Oxidation Number: The oxidation number of an atom is a measure
of its electron state. An increase in oxidation number indicates oxidation,
while a decrease indicates reduction.
● Balancing Redox Equations: Redox equations must
be balanced to ensure that the number of electrons lost by the reducing agent
equals the number of electrons gained by the oxidizing agent.
● Applications: Redox reactions are essential in various
processes, including:
○ Corrosion
○ Combustion
○ Electrochemistry
○ Metabolism
Example of a Redox
Reaction:
The reaction between zinc metal and copper(II) ions is a classic redox
reaction:
Zn(s)
+ Cu²⁺(aq) → Zn²⁺(aq) + Cu(s)
In this reaction, zinc metal loses two electrons (oxidation) to become Zn²⁺ ions, while Cu²⁺ ions gain two electrons (reduction) to become copper metal.
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